you can launch other apps from within App Inventor with the Activity Starter.
See also more info about Using the Activity Starter here.
Starting arbitrary apps
You can use the Activity Starter to start any activity at all if you know the package name and class name, or the appropriate intent. Some developers document these intents for the benefit of other Android developers. For hints on starting other apps using intents, see the Android API documentation or search the Android developer forums.
If you have an app on your phone and you don't have the source code, you might still be able figure out the package name and class name (and sometimes the intent) by launching the app and inspecting the Android system log, as indicated above.
UPDATE: You meanwhile can find a small tutorial "How to save a text file to SD card using the Activity Starter calling a Java app" here