use the mysql_fetch_array() method to extract the data from your query resource:
$emailcheck = $_POST['email'];
$checkit = mysql_query("SELECT Security_Question FROM users WHERE email ='$emailcheck'"); //fixed query syntax*
if (!$checkit) exit(); //don't forget to catch query errors!
$result = mysql_fetch_array($checkit);
$question = $result['Security_Question'];
$question
will hold the security question.