I wouldn't try to replicate or share data from CouchDB to MySQL. CouchDB has a significantly different data model than MySQL, so at best you end up with a pretty bad mismatch between data on both sides.
On the other hand, making a well-designed PHP-based website interface with CouchDB instead of MySQL shouldn't be that hard. The CouchDB REST API is pretty easy to work with, and there are plenty of libraries you can use.