If you want to do this dynamically by fetching the values from the listbox simply put the listbox inside a form whose action is pointing the controller action you want to invoke and then use a submit button. HTML will then do the job for you.
If you want to generate an ActionLink you could use the following:
@Html.ActionLink(
"TestLink",
"Index",
New RouteValueDictionary() From {
{ "fields[0]", "value1" },
{ "fields[1]", "value2" }
}
)