What you're looking for is the STCentroid() method but, unfortunately, it doesn't work for MultiPoint objects. I raised a Connect issue for this a few years back which has been closed by Microsoft as "Won't Fix", but you're welcome to vote it up anyway: https://connect.microsoft.com/SQLServer/feedback/details/588316/make-geometry-stcentroid-method-work-on-geometries-other-than-polygons
Meanwhile, you'll have to manually sum and then average the X and Y coordinate values individually to get the average "centre" of a Multipoint.