I have managed to work it out with some help from one of the users on the official Wunderground forum. Here is the new code that i am using with a few more added bits.
jQuery('#GetWeather').click(function() {
var PostCode=" ";
$.ajax({ url : "http://api.wunderground.com/api/2508132ae0c7601a/geolookup/forecast/q/UK/"+PostCode +".json",
dataType : "jsonp",
success : function(parsed_json) {
var Forcast = parsed_json['forecast']['simpleforecast']['forecastday'];
for (index in Forcast) {
var imageurl = "http://.....";
/* Weather Box 0 Day 1, 1st period */
$('.Wicon').css('background-image',"url("+imageurl+Forcast[0]['icon']+".svg)");
$('#GetWeatherDay').html(Forcast[0]['date']['weekday']);
$('#GetWeatherState').html(Forcast[0]['conditions']);
$('#GetWeatherTempHigh').html('High of '+Forcast[0]['high']['celsius']+'℃');
$('#GetWeatherTempLow').html('Low of '+Forcast[0]['low']['celsius']+'℃');
$('#GetWeatherMaxWind').html('Max Wind '+Forcast[0]['maxwind']['mph']+' Mph');
$('#GetWeatherAveWind').html('Average Wind '+Forcast[0]['avewind']['mph']+' Mph');
$('#GetWeatherWindDir').html('Wind Direction '+Forcast[0]['avewind']['dir']);
$('#GetWeatherHumidityA').html('Average '+Forcast[0]['avehumidity']+'%');