The registration authority for MAC addresses is the IEEE. It hands out OUIs (Organizationally Unique Identifiers), which give you a three byte prefix, and 2^24 addresses within it, for a fee (currently 2 995USD). You also get the rights to the corresponding multicasts, which have the prefix with the lowest bit of the first byte set. For instance, 00:80:C2 is allocated to the IEEE 802.1 committee, which uses 01:08:C2:00:00:00 for Spanning tree.
So, there isn't really a list of reserved addresses. There is a list of OUIs that have been allocated, unless the buyer has paid (a lot) extra for privacy. You can use any address that has the local bit set freely. A tiny fraction of multicast addresses have a significant meaning because heavyweights like IEEE, Cisco, IANA assign meanings to them. From the IEEE registration point of view, there is no particular significance to these blocks (except possibly to those it has allocated to itself).
Now, how did the 01-00-5E range end up allocated to the Information Sciences Institute? The simple
answer is that they paid for it. So, really the question should be 'how did the Internet get to use part of the range allocated to ISI?'. The answer is that the IANA used to be run from an office in ISI: specifically IANA was the legendary Jon Postel
Bottom line: you are on a bit of a fool's errand. You can distinguish local addresses and multicast addresses, and make some attempt to tie up allocated unicast addresses to vendor blocks. And you can probably do a bit more with well-known multicast addresses but only by tracking down individudal vendor's documentation (IANA is obviously an important one but only definitive for 1 of the 2^22 available blocks). One of the best places to start is probably the Wireshark codebase.