You can use the following URL. Change Latitude and Longitude based on your requirement.
http://api.wunderground.com/auto/wui/geo/GeoLookupXML /index.xml?query=17.3820420000000000006,78.48172729999999000
To get the current weather condition you can use the following API endpoint. The only thing you have to Generate API key from their site. - http://www.wunderground.com/weather/api
Here is the endpoint : http://api.wunderground.com/api/API_KEY/conditions/forecast/alert/q/17.382042000000000000,78.48172729999999000.json
Replace the API_KEY from you generated API key.