Yes you can, here is a simple guide taken from here https://zignar.net/2012/06/17/install-python-on-windows/
Before you can install Pip, you'll need setuptools or distribute. If you're using Python3, you must use distribute as setuptools doesn't support Python 3.x
To install distribute download the setup file here https://pypi.python.org/pypi/distribute/0.6.27 and invoke it using python.
python.exe C:\Path\to\distribute_setup.py
Now that distribute is installed, Pip can also be installed. Download get-pip.py here https://raw.github.com/pypa/pip/master/contrib/get-pip.py and invoke it in the same way you invoked distribute_setup:
python.exe c:\Path\to\get-pip.py
After that Pip is installed. But you might want to add C:\Python32\Scripts to the Path Systemvariable too (see step 1). So you can execute pip.exe from any location.