You have to go 2 steps:
First: Resolve the items and create the text
SELECT
orderform.order_id AS order_id,
CONCAT(orderform.quantity, ' x ',item.name) AS txt
FROM order orderform
LEFT JOIN item ON orderform.item_id = item.item_id
then group by order
SELECT
order_id,
group_concat(txt) AS txt
FROM (
SELECT
orderform.order_id AS order_id,
CONCAT(orderform.quantity, ' x ',item.name) AS txt
FROM order orderform
LEFT JOIN item ON orderform.item_id = item.item_id
) AS baseview
GROUP BY order_id