Yes, here are links to the documentation:
- http://support.nservicebus.com/customer/portal/articles/894008-using-nservicebus-with-asp-net-mvc
- http://support.nservicebus.com/customer/portal/articles/894123-injecting-the-bus-into-asp-net-mvc-controller
You can also have a look at our sample projects for examples on how to do it, see https://github.com/NServiceBus/NServiceBus/tree/master/Samples/AsyncPagesMVC3
There is also a sample that uses MVC4 but that is against NServiceBus v4 which has not been released yet, see https://github.com/Particular/NServiceBus/tree/develop/Samples/VideoStore.Msmq/VideoStore.ECommerce