/usr/ccs/lib/cpp is not the XL C/C++ for AIX compiler, it is the C Pre-Processor which ships as part of AIX. The XL C/C++ for AIX compiler is a separate Licensed Program Product for which licenses must be separately purchased.
If you have XL C/C++ for AIX installed, you would find the /usr/vac/bin/xlc and /usr/vacpp/bin/xlc++ commands installed on your system. You can also check for the filesets vac.C and vacpp.cmp.core using the lslpp command:
lslpp -L vac.C vacpp.cmp.core