You can just invoke the method manually
NSSplitView * yourSplitView; //Get reference to your splitview
id yourSplitViewDelegate = [yourSplitView delegate];
[yourSplitViewDelegate splitViewWillResizeSubviews:nil];//Optionally create the NSNotification with relevant data
If you really want to go through notification center, make sure self
in your question is the NSSplitView.
NSSplitView * yourSplitView; //Get reference to your splitview
[[NSNotificationCenter defaultCenter] postNotificationName:NSSplitViewWillResizeSubviewsNotification object:yourSplitView];