What version of FSharp.Data are you using? I just tried this with 1.1.4 and it worked fine:
let feed = XmlProvider<"http://squarism.com/feed/atom/">.GetSample()
let entries = feed.GetEntries()
There was a problem with Xml namespaces that was recently fixed (see SO question)
In any case, the place to put the breakpoint is here (in the FSharp.Data.dll
assembly, not FSharp.Data.DesignTime.dll
assembly)
If 1.1.4 doesn't work please submit an issue on GitHub