getElementById returns null if it can't find an element with the supplied ID. A more robust method (i.e. one that wont throw errors) is:
var button = document.getElementById("submit_btn"); // spelling of "submin_btn"?
if (button) button.value = "Sending...";
However, if the button is in a form, likely you will not see the value change in some if not most browsers. When a form submits (or navigation away from the current page begins) they cease updating the visible DOM (likely they figure "what's the point?").