Icon sizes are listed here:
The biggest shock for me, when submitting an app after a hiatus, was the 1024x1024 App Store icon. Who has artwork that big???
You will also need double-resolution screen shots for all device sizes (iPhone 4, iPhone 5, and iPad).
My book has a pretty good checklist of the things you'll need as part of your final preparations before submission:
http://www.apeth.com/iOSBook/ch09.html#_final_app_preparations