The "error" pylint reports on PyQT import is because since PyQT has some C++ or some C in it, pylint cannot easily and automatically introspect the PyQt module and determine if your code correctly imports bits of that 3rd party module.
To solve that, there is an plugin project to pylint called pylint-brains into which one can specify ways of introspecting specific modules (or faking their introspection). It would be nice to have a contribution that would remove the "E" of this pretty common import.
For the ImportError, as discussed in the comments, I believe either you have to re-install PyQt for this version of python or PyQt is not yet compatible with 3.3, or something in your pythonpath is wrong.