You can retrieve the API documentation here. This is ACS' proprietary APDUs so don't refer to standard ISO-7816 specification. Refer to section 6 for pseudo-APDU requirements.
To simulate LED, refer to section 6.2 for details and appendix E for example. You may try changing your APDU as follow: FF 00 40 FF 04 0A 0A 03 03. Please note that I set the LED control and also put non-zero values for LED duration.
For the second APDU, refer to section 4. Please note that you are missing P3/Le in your APDU (shall be FF CA 01 00 00) and you need the card reader connected with PICC.