I'm pretty sure you can't do that without instrumenting the locks, or something similar.
One could come up with a lot of scenarios where the call of a locking function causes different behaviour in testing [possibly only when "special test-mode for identifying testing" is enabled] than in production code - for example, add a sleep for 100ms into the lock method, and try to use another locked function and compare the time with "no competiton for the lock.
Or we could keep a count of calls to lock, and see if the count before and after the function is the same (or has increased by the expected amount, if the function is supposed to call lock
a certain number of times).
But a generic way that isn't intrusive into the locking mechanism, I'm pretty sure it's impossible.
Of course, code-review and clear documentation as to what code calls locks and which doesn't would also be useful - and good reviewers that spot errors.