There is nothing exactly like you are looking for in Visual Studio 2012 Professional. If you are working in a C# project, you can automatically get a code map similar to what you are looking for with the "Go To Definition" feature.
Here is a snippet of C# code.
Pressing F12 while the cursor is on the StreamReader class causes the following metadata editor to open.
Use Go To Definition to decode VB class
The VB editor also has a Go To Definition, but it takes you to the Object Browser instead of the metatdata window. But there is a way to get the metadata.
Create a separate C# project. In my example, I made a simple Console application. Add a reference to your VB project Write some code in the C# project to instantiate a type in the VB library and use the C# F12 to get the metadata
Here is a simple VB class.
This is the C# code referring to the Printer class.
Here is the metadata from the VB class, from within the C# project.
I know this is not as complete as your example, but it's a start.
Other solutions
There is a Code Map extension you can install from the Tools\Extensions and Updates
menu. I don't think it supports the printing option you want however.
Finally, you can create your own Visual Studio extension. This is not a trivial task though. Download the Visual Studio SDK if you want to learn more.