From where you are:
Minutes = c(2:7:end);
MinuteValues=unique(Minutes);
Prices = c(5:7:end);
if (length(Prices)>length(Minutes))
Prices=Prices(1:length(Minutes));
elseif (length(Prices)<length(Minutes))
Minutes=Minutes(1:length(Prices));
OverflowValues=1+find(Minutes(2:end)==0 & Minutes(1:end-1)==59);
for v=length(OverflowValues):-1:1
Minutes(OverflowValues(v):end)=Minutes(OverflowValues(v):end)+60;
end
Highs=zeros(1,length(MinuteValues));
Lows=zeros(1,length(MinuteValues));
First=zeros(1,length(MinuteValues));
Last=zeros(1,length(MinuteValues));
for v=1:length(MinuteValues)
Highs(v) = max(Prices(Minutes==MinuteValues(v)));
Lows(v) = min(Prices(Minutes==MinuteValues(v)));
First(v) = Prices(find(Minutes==MinuteVales(v),1,'first'));
Last(v) = Prices(find(Minutes==MinuteVales(v),1,'last'));
end
Using textread would make this easier for you, as mentioned.
(If you are lost at this stage, I wouldn't find accumarray as mentioned in the comments is the best place to start!)
By the way, this is assuming that minutes increases above 60 and you don't have hours in there somewhere. Otherwise this won't work at all.