I know of two iOS EPUB3 readers these are iBooks and Gitden reader.
EPUB3 must contain a navigation file based on HTML5 See: http://www.heliconbooks.com/article/epub3navdoc
You can simply display this file as standard HTML file, however notice that this file must contain semantic tags like There may be more then one section in each TOC file. This file is pointed to by the OPF file, in the manifest section there should be one and only one item with property="nav"