This string "xVF79DzOplxBTMCwAx+hoeDJhyhifPZEoACQJcFhrXA=" is a base64-encoded value.
https://en.wikipedia.org/wiki/Base64
Base64 encoding is widely used lots of applications, it's a good way to encode binary data into text. If you're looking at a long encoded value, the "=" at the end can be a good indicator of base64 encoding.
In your python code you probably need to base64 decode the data before handing it to the decryption function.
I have two recommendations:
If crypto isn't a comfort zone for you, consult with someone who is good in this area for your project.
Be aware that embedding a symmetric encryption key in an Android app that you distribute is a bad idea. Anyone that can get a copy of your app can extract that key and use it to decrypt or spoof your messages.