If order to send a file as an attachment with iOS Mail, you need to set the MIME type of the file. According to this web site, one of the MIME types used for WAV is audio/wav.
- (void)mailMe {
// recipient address
NSString *email = mailaddress;
NSMutableArray *toRecipient = [[NSMutableArray alloc]initWithObjects:nil];
[toRecipient addObject:email];
MFMailComposeViewController *mc = [[MFMailComposeViewController alloc] init];
mc.mailComposeDelegate = self;
// attachment
NSData *data = [NSData dataWithContentsOfFile:[self filePathAudio]];
[mc addAttachmentData:data mimeType:@"audio/wav" fileName:@"MyAudioMemo.wav"];
// subject
[mc setSubject:mailsubject];
// message
[mc setMessageBody:msgbody isHTML:NO];
[mc setToRecipients:toRecipient];
[self presentViewController:mc animated:YES completion:NULL];
}