String input = ":-) :) :o) :] :3 :c) :> =] 8) =) :} :^)";
String[] similies = input.split(" ");
for (String simili : similies) {
System.out.println(simili);
}
This works fine. Output :
:-)
:)
:o)
:]
:3
:c)
:>
=]
8)
=)
:}
:^)
and in case if there is any tab/newline/spaces and you wnat to split, in that case you can use
input.split("\\s+");
in your example there is few more charaters are their like  and non breaking whitespaces so you have to explicitly handle these type of charater. Here is the code:
public static void main(final String[] args) throws Exception {
BufferedReader fileReader = new BufferedReader(new FileReader("emoticon.txt"));
String line = "";
while ((line = fileReader.readLine()) != null) {
line = line.replaceAll("Â", "");
line = line.replace("" + ((char) 160), " ");
System.out.println("line: " + line);
String[] icons = line.split("\\s+");
for (String icon : icons) {
System.out.println(icon);
}
System.out.println("=======================");
}
}