There are some issues with using pow and rbenv as chronicled here: rbenv does not work well with pow
The problem seems to center on some PATH issues with the powconfig file, hence the reason pow is trying to use your default ruby install (assuming 1.9.x) vs. what you designated via rbenv. If you are using OSX mavericks, add the following to your ~/.powconfig file, restart pow once the change is made, and you should be good to go. (per the last suggestion):
export RBENV_ROOT=/usr/local/var/rbenv # Might not be necessary for pre-Mavericks OSX
eval $(rbenv init -)
export PATH=$(rbenv root)/shims:$(rbenv root)/bin:$PATH