Most likely value is not blank string but a Nothing
. Try following construct:
=IIf(IsNothing(((Sum(Fields!TotalCost.Value, "Accrued") + Sum(Fields!TotalCost.Value, "serv1")) / (Sum(Fields!Quantity.Value, "serv1") + Sum(Fields!Quantity.Value, "Accrued"))), 0, ((Sum(Fields!TotalCost.Value, "Accrued") + Sum(Fields!TotalCost.Value, "serv1")) / (Sum(Fields!Quantity.Value, "serv1") + Sum(Fields!Quantity.Value, "Accrued")))
It's a bit awkward since you have to repeat the expression twice, to avoid it you may want to write a custom function.