I assume you have the ability to edit one of the config files to enable extensions, such as the .hgrc file. If that is true, then as described here or here you can add the following (and ensure the path to diffmerge is correct):
[ui]
merge = diffmerge
[extensions]
hgext.extdiff =
[extdiff]
cmd.diffmerge = /usr/bin/diffmerge
[merge-tools]
diffmerge.executable = /usr/bin/diffmerge
diffmerge.args = -merge -result=$output -t1="Local Version" -t2=$output -t3="Other Version" -caption=$output $local $base $other
diffmerge.binary = False
diffmerge.symlinks = False
diffmerge.gui = True
Since you only asked to add it to diff between files and not for merging, you may only need the following sections (which excludes the merge functions) :
[extensions]
hgext.extdiff =
[extdiff]
cmd.diffmerge = /usr/bin/diffmerge