With this setting you cannot access the LoginController.php, because it differs from the DocumentRoot.
DocumentRoot = C:/wamp/www/Duplicate/Views/
File = C:/wamp/www/Duplicate/Controllers/LoginController.php
Direct access should only be possible for files, that are in the DocumentRoot (or any of its subfolders).
You maybe can change your DocumentRoot to "C:/wamp/www/Duplicate/" and put an index.php in that folder that redirects you to "Views/".