Try PreviewMouseLeftButtonDown
<TabItem Header="Manage Users" Visibility="{Binding IsAdmin, Converter={StaticResource VisibilityOfBool}}">
<i:Interaction.Triggers>
<i:EventTrigger EventName="PreviewMouseLeftButtonDown">
<i:InvokeCommandAction Command="{Binding Path=OpenLoginCommand}"/>
</i:EventTrigger>
</i:Interaction.Triggers>
</TabItem>