Any of the control characters should be good for this, such as TAB, FF and so on.
RFC3986 (a) controls the URI specification and Appendix A of that RFC states that the characters are limited to:
ABCDEFGHIJKLMNOPQRSTUVWXYZabcdefghijklmnopqrstuvwxyz
0123456789-._~:/?#[]@!$&'()*+,;=
(and the %
encoding character, of course, for all other characters not listed above).
So, basically, any other character should be okay as a delimiter.
(a) This has actually been augmented by RFC6874 which has to do with changes to the IPv6 part of the URI, adding a zone identifier. Since the zone ID consists of %
and "unreserved" characters already included above, it doesn't change the set of characters allowed.