I found this while trying to solve a similar problem: Rally chart documentation
If you use the updateBeforeRender option, you can reference Highcharts, specifically the method:
Highcharts.setOptions();
which is what you need to use something like the gray theme.
Here is what my chart config looks like:
App.down('#chartContain').add({
xtype: 'rallychart',
updateBeforeRender: function() {
Highcharts.theme = {...}
Highcharts.setOptions(Highcharts.theme);
}
...
}
Copy the theme code from the Highcharts documentation and you should be good to go!