I would create a property to access like
Code Behind
string _selectedValue;
public string SelectedValue {
get { return _selectedValue; }
}
Set the '_selectedValue' as your grdFlights.SelectedDataKey.Value
Then in the .aspx page you can do
var value = <%# SelectedValue%>;
onclientclick="window.open('../Prints/EASYBRIEF.aspx?' + value)"
Something to that effect.