You need something like this:
Sub iniCreate()
For iCol = 1 To 3
Open Environ("UserProfile") & "/MyProg" & Range("B1").Offset(0, iCol - 1).Value _
& ".ini" For Output As #1
For jRow = 1 To 16
Print #1, Range("A2").Offset(jRow - 1, 0); Range("A2").Offset(jRow - 1, iCol)
Next jRow
Close #1
Next iCol
End Sub
I used random numbers as data so it looked like this:
V000 V001 V002
UseMct= 0.659099708 0.098897863 0.66830137
UseCellular= 0.081138532 0.064777691 0.919835459
UseKvh= 0.942430093 0.872116053 0.032414535
UseIridium= 0.263586179 0.921751649 0.295967085
UseAurora= 0.867225038 0.094161678 0.11271394
UseSailor= 0.112345073 0.247013614 0.562920243
SailorUnitAddress= 0.641083386 0.630124454 0.430450477
AuroraUnitAddress= 0.133569751 0.431081763 0.620952387
QualcommSerialPort= 0.489904861 0.745152668 0.0371556
MctUnitAddress= 0.390312141 0.643551357 0.621789056
CellularUnitAddress=0.924394826 0.672907813 0.834973453
KvhSerialPort= 0.431335182 0.040557434 0.329205484
KvhUnitAddress= 0.018331225 0.405080112 0.281003
IridiumUnitAddress= 0.530083065 0.428947849 0.781832847
IridiumPositionUrl= 0.473567159 0.428633715 0.00044413
HostUrl= 0.132253798 0.832369002 0.981755331
The V000, V001 etc form part of the file name. E.g. MyProgV000.ini I use the UserProfile environment variable to select an output folder. You can choose another one if you prefer.
Then the two For Loops just output the data to the file.