It had to do with ownership. One or the other has worked [for reasons that are not clear to me]:
chown www-data:www-data /var/log/php_error.log
chown same-user-as-www-home:same-user-as-web-home /var/log/php_error.log
Also, the following has made a difference:
chmod 664 /var/log/php_error.log
[as opposed to chmod 644...again for reasons that are not clear to me]