To assign an attached property as an inner tag you simply use the name of the attached property:
<Polygon>
<Canvas.Left>
<MultiBinding>
...
</MultiBinding>
</Canvas.Left>
</Polygon>
If you've worked with Blend and the interactions library, then you'd see this is exactly how it works there as well (here Triggers
is in fact an attached property):
<Control>
<i:Interaction.Triggers>
...
</i:Interaction.Triggers>
</Control>