Try like this,
SELECT i.index_name,
c.column_position,
c.column_name,
i.uniqueness
FROM sys.all_indexes i,
sys.all_ind_columns c
WHERE i.table_name = 'MY_TABLE'
AND i.owner = 'ME'
AND i.uniqueness = 'UNIQUE'
AND i.index_name = c.index_name
AND i.table_owner = c.table_owner
AND i.table_name = c.table_name
AND i.owner = c.index_owner
AND c.index_name IN (SELECT index_name FROM sys.all_ind_columns WHERE column_position = 2);