What are you reading from the files are simply characters codes: the program has no way of figuring by itself that the character "4" corresponds to the integer number 4. The %d placeholder of printf expects int variables, or it won't work.
If you want just to print the characters you have to save them in char variables (or a char array) and use the placeholder %c in printf. If you want to actually use the numbers and symbols in your program you have more work to do.
Not only in C, but I think in most languages you have to "parse" the characters to numbers.
In C you can use the functions atoi or atol (you have to #include <stdlib.h>
) in order to do this conversion.
In order to parse the symbol I'm afraid you will have to use an if or a switch to read the character and perform the operation accordingly.
For example your loop could look like:
while(fgets(line,sizeof line,f)!=NULL)
{
int op1;
int op2;
int res;
char symbol;
i++;
switch (i) {
case 1:
//First line is first operand
op1 = atoi(line);
printf("op1 %d\n",op1);
break;
case 3:
//Second line is second operand
op2 = atoi(line);
printf("op2 %d\n",op2);
break;
//Fifth line is the operator, could be +,-,%./ or anything
case 5:
symbol = line[0];
printf("operand %c\n",symbol);
switch(symbol) {
case '+':
res = op1+op2;
break;
case '-':
res = op1-op2;
break;
default:
//operation not defined, return
return;
}
printf("%d%c%d = %d",op1,symbol,op2,res);
}
}