You will always get css validation error while using CSS3. Most of the styles(css3) are not valid under w3 rules as of now.. You can simply ignore these errors and move ahead.. Just make sure you do not have any other validation issues other than those with css3 styles. If so you are perfectly fine..
Update :
You can try something like this :
http://jigsaw.w3.org/css-validator/validator?profile=css3&uri=PATH_TO_YOUR_WEBSITE
For eg :
http://jigsaw.w3.org/css-validator/validator?profile=css3&uri=http://stackoverflow.com
Still it will show lot of errors. There are no CSS3 validators yet implemented which is accepted.
[Updated]
URL : https://validator.w3.org/
Please use the official validator.