Well, a list of all operators makes as much sense as a list of all methods in the library, regardless of the type. It isn't going to be particularly useful except for finding information about a specific operator.
However, if you do want one, at any ScalaDoc site (http://www.scala-lang.org/api/current/ for the standard library) there is an alphabetic index just under the search bar. The first link (#
) lists all the non-alphabetic methods (i.e. "operators").
Many of these are rarely used, or only in specific circumstances.
Obviously, any other library can introduce its own operators, and you'll need to check its own documentation.