"don't hard code your providers" discusses this in detail.
It shows a setting like what you want:
<add name="blah" providerName="Npgsql"
connectionString="Server=127.0.0.1;Port=5432;Database=myDataBase;
User Id=myUsername;Password=myPassword;"/>
but then explains why you should not do this, you should read the settings from your application's configuration file at runtime instead.