Multi-level certificate means which is signed by some other CA. Single-level certificate means certificate signed by itself which is also known as self-signed certificate.
Means, if you can check if the certificate is self-signed, then you can tell if it is single or multi-level.
To check quickly if certificate is self-signed, you can use following command:
openssl verify -CAfile cert.crt cert.crt
Where cert.crt is your certificate in PEM format.
If it tests okay, then it is self signed and hence single level. Otherwise, multi-level.
You can also write C program to verify if your certificate is self signed or using X509_verify
function.