If you want to select the first row of a set of rows with the same characteristics, you can use the ROW_NUMBER() function and PARTITION BY clause. Something like this:
SELECT * FROM (
SELECT *, ROW_NUMBER() OVER (PARTITION BY CNum, CUID ORDER BY Id) AS ROWNUM
FROM Con
) x WHERE x.ROWNUM = 1
The subquery adds a row number to each row having the same values for CNum/CUID.