Segmentation Fault and Memory Corruption with pointer to array of pointers

Question

The objective here is to have a pointer that works like a 2D matrix. I've tested the following bit of code for creating a pointer to and array of integer pointers. It compiles and runs fine. (This is a simplified version, I've tried assigning/printing values to mymatrix[x][y] and it works fine.)

#include <iostream>
int **mymatrix;

int main(int argc, char* args[]){

  mymatrix = new  int*[100] ;
  for( int n = 0; n <= 100; n++ ){
    mymatrix[n] = new int[200] ;
  }
  return 0;
}

However, as soon as I copy this snippet to another code (which previously ran fine), the code still compiles but fails to run. There are no errors or warnings related to this snippet. This is weird because mymatrix doesn't even interact with the rest of the code yet (after being defined it's just never used again).

The actual error which interrupts the execution varies between crashing when trying to load a font, Segmentation Fault when trying to assign a value, and Memory Corruption (with a huge log output of what I think are threads).

I could paste sections of the larger code, but I'm almost convinced that this is all happening because I'm not defining this pointer in the proper way. Am I doing something clumsy or unsafe here? Or should I start looking through the rest of my code for bugs?