this is very well explained here.
Shortly: with EF5 (to be more specific, with .net 4.5) Microsoft included the type DbGeography. Let say you already have a bunch of lat/long, you can then create a DbGeography object easily using an helper like:
public static DbGeography CreatePoint(double latitude, double longitude)
{
var text = string.Format(CultureInfo.InvariantCulture.NumberFormat,
"POINT({0} {1})", longitude, latitude);
// 4326 is most common coordinate system used by GPS/Maps
return DbGeography.PointFromText(text, 4326);
}
Once you got a two or more points (DbGeography) you got everything to calculate the Distance between them:
var distance = point1.Distance(point2)