Try saving the solution in a variable first:
e = NDSolve[{D[c[t, h], t] == 1*D[c[t, h], h, h], c[0, h] == Erfc[h/(2*81.2)], c[t, 0] == 1, c[t, 4000] == 3.08*^-18}, c, {t, 0, 900}, {h, 0, 274}]
Then we can Evaluate this expression for our desired variables:
Evaluate[c[900, 10] /. e]
(*{0.914014}*)
Or to make it more versatile, we can use Manipulate:
Manipulate[Evaluate[c[t, h] /. e], {t, 0, 900}, {h, 0, 274}]
Update: Considering the information I received from the comments below; we can define a function like q[t,h] which will give us the solution as a function:
q[t_, h_] := Evaluate[c[t, h] /. e]
q[900, 10]
(*{0.914014}*)