Replace following code for your button click event :
private void btnRot_Click(object sender, EventArgs e)
{
if (Spielzuege2 >= 16)
{
_Stopwatch2.Stop();
_ReactionTimes2.Add(_Stopwatch2.Elapsed);
labelSummary2.Text = String.Format("Player 2: Current: {0:0.000} s Minimum: {1:0.000} s Maximum: {2:0.000} s", _ReactionTimes2.Last().TotalSeconds, _ReactionTimes2.Min().TotalSeconds, _ReactionTimes2.Max().TotalSeconds);
}
else
{
_Stopwatch.Stop();
_ReactionTimes.Add(_Stopwatch.Elapsed);
labelSummary.Text = String.Format("Player 1: Current: {0:0.000} s Minimum: {1:0.000} s Maximum: {2:0.000} s", _ReactionTimes.Last().TotalSeconds, _ReactionTimes.Min().TotalSeconds, _ReactionTimes.Max().TotalSeconds);
}
}