send request using this function
[xmppStream sendElement:iq];
and create your iqbookmark object as follows
NSString* server = @"test@pc"; //or whatever the server address for muc is
XMPPJID *servrJID = [XMPPJID jidWithString:server];
XMPPIQ *iq = [XMPPIQ iqWithType:@"set" to:servrJID];
// [iq addAttributeWithName:@"from" stringValue:[xmppStream myJID].full];
[iq addAttributeWithName:@"id" stringValue:@"123"];
NSXMLElement *query = [NSXMLElement elementWithName:@"query"];
[query addAttributeWithName:@"xmlns" stringValue:@"jabber:iq:private"];
NSXMLElement *storage_q = [NSXMLElement elementWithName:@"storage"];
[storage_q addAttributeWithName:@"xmlns" stringValue:@"storage:bookmarks"];
NSXMLElement *conference_s = [NSXMLElement elementWithName:@"conference"];
[conference_s addAttributeWithName:@"name" stringValue:@"roomExample1_satish"];
[conference_s addAttributeWithName:@"autojoin" stringValue:@"true"];
[conference_s addAttributeWithName:@"jid" stringValue:@"roomExample1@conference.test@pc"];
[conference_s addAttributeWithName:@"nick" stringValue:@"satish"];
[storage_q addChild:conference_s];
[query addChild:storage_q];
[iq addChild:query];