Just add the following code into your "woocommerce-export-csv.php"
add_filter( 'woocommerce_export_csv_extra_columns', 'sites_add_custom_meta', 10);
and the define your function
function sites_add_custom_meta() {
$custom_meta_fields['columns'][] = 'IP Address';
$custom_meta_fields['data'][] = '_customer_ip_address';
return $custom_meta_fields;
}
In this function you have two things you need to define. First, in the columns array you need to define the titles of your custom meta fields and then in the data array you need to define actual meta field name where the data for that field is located at. You need to have the same order in both arrays to be able to have correct information output under right column title.
Source : http://docs.woothemes.com/document/ordercustomer-csv-exporter/#section-4