you need this:
var query = (from t1 in tb1
join t2 in tb2 on t1.pKey = t2.tb1pKey into JoinedList
from t2 in JoinedList.DefaultIfEmpty()
where t1.userID == 5 && t1.status == "CL"
select new
{
t1,
t2
})
.ToList();